Hydrogen Peroxide 50% 35KG

Hydrogen Peroxide 50% – Product Identifier

Product Name Hydrogen Peroxide 50%

Other means of identification: CAS-No 7722-84-1

Recommended use of the chemical and restrictions on use

Recommended Use:

Restrictions on Use:

Manufacturer/Supplier

Potable water treatment: Certified to conform to the requirements of the “NSF / ANSI

Standard 60 – Drinking Water Treatment Chemicals – Health Effects” by NSF International

Use as recommended by the label
Hydrogen Peroxide 50% – Hazards Identification

Classification

OSHA Regulatory Status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Acute toxicity – Oral Category 4

Acute toxicity – Inhalation (Vapors) Category 4

Skin corrosion/irritation Category 1 Sub-category B

Serious eye damage/eye irritation Category 1

Specific target organ toxicity (single exposure) Category 3
Hydrogen Peroxide 50% – GHS Label elements, including precautionary statements

EMERGENCY OVERVIEW

Precautionary Statements – Prevention

P271 – Use only outdoors or in a well-ventilated area

P260 – Do not breathe mist, vapours or spray.

P280 – Wear protective gloves/ protective clothing/ eye protection/ face protection

P210 – Keep away from heat/sparks/open flames/hot surfaces. – No smoking

P220 – Keep/Store away from clothing/flammable materials/combustibles

P221 – Take any precaution to avoid mixing with combustibles/flammables

Precautionary Statements – Response

P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 – Immediately call a POISON CENTER or doctor

P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower

P363 – Wash contaminated clothing before reuse

P304 + P340 – IF INHALED: Remove person to fresh air and keep comfortable for breathing

P312 – Call a POISON CENTER or doctor if you feel unwell

P301 + P330 + P331 – IF SWALLOWED: rinse mouth. Do NOT induce vomiting

P310 – Immediately call a POISON CENTER or doctor

P370 + P378 – In case of fire: Use water for extinction

Hazards not otherwise classified (HNOC)

No hazards not otherwise classified were identified.
Hydrogen Peroxide 50% – Other Information

Keep container in a cool place out of direct sunlight. Store only in vented containers. Do not store on wooden pallets. Do not return unused material to its original container. Avoid contamination – Contamination could cause decomposition and generation of oxygen which may result in high pressure and possible container rupture. Empty drums should be triple rinsed with water before discarding.

.

Oxidizing Liquids Category 2

Danger

Hydrogen Peroxide 50% – Hazard Statements

H314 – Causes severe skin burns and eye damage

H302 – Harmful if swallowed

H332 – Harmful if inhaled

H335 – May cause respiratory irritation

H272 – May intensify fire; oxidizer
Hydrogen Peroxide 50% – FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Seek

immediate medical attention/advice.

Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20

minutes. Call a poison control center or doctor for further treatment advice.

Inhalation Move to fresh air. If person is not breathing, contact emergency medical services, then give

artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or

doctor for further treatment advice.

Ingestion Rinse mouth. Do not induce vomiting. If conscious, give 2 glasses of water. Get immediate

medical attention. Never give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed

Hydrogen Peroxide irritates respiratory system and, if inhaled, may cause inflammation and

pulmonary edema. The effects may not be immediate. Overexposure symptoms are

coughing, giddiness and sore throat. In case of accidental ingestion, necrosis may result

from mucous membrane burns (mouth, esophagus and stomach). Oxygen rapid release

may cause stomach swelling and hemorrhaging, which may product major, or even fatal,

injury to organs if a large amount has been ingested.

In case of skin contact, may cause burns, erythema, blisters or even necrosis.

Indication of immediate medical attention and special treatment needed, if necessary

Hydrogen peroxide at these concentrations is a strong oxidant. Direct contact with the eye

is likely to cause corneal damage especially if not washed immediately. Careful

opthalmologic evaluation is recommended and the possibility of local corticosteroid therapy

should be considered. Because of the likelihood of corrosive effects on the gastrointestinal

tract after ingestion, and the unlikelihood of systemic effects, attemps at evacuating the

stomach via emesis induction or gastric lavage should be avoided. There is a remote

possibility, however, that a nasogastric or orogastric tube may be required for the reduction

of severe distension due to gas formation.
FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Water. Do not use any other substance.

Specific Hazards Arising from the Chemical

In closed unventilated containers, risk of rupture due to the increased pressure from

decomposition. Contact with combustible material may cause fire

Hazardous Combustion Products On decomposition product releases oxygen which may intensify fire.

Explosion data

Sensitivity to Mechanical Impact Not sensitive.

Sensitivity to Static Discharge Not sensitive.

Protective equipment and

precautions for firefighters

Use water spray to cool fire exposed surfaces and protect personnel. Move containers from

fire area if you can do it without risk. As in any fire, wear self-contained breathing apparatus

and full protective gear.
ACCIDENTAL RELEASE MEASURES

COMPOSITION/INFORMATION ON INGREDIENTS

Formula HO – OH

Chemical name CAS-No Weight %

Hydrogen peroxide 7722-84-1 50

Water 7732-18-5 50

Occupational exposure limits, if available, are listed in section 8
Personal Precautions Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Isolate and

post spill area. Keep people away from and upwind of spill/leak. Eliminate all sources of

ignition and remove combustible materials.

Other Combustible materials exposed to hydrogen peroxide should be immediately submerged in

or rinsed with large amounts of water to ensure that all hydrogen peroxide is removed.

Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can

concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other

combustibles can cause the material to ignite and result in fire.

Environmental Precautions See Section 12 for additional Ecological Information.

Methods for Containment Dike to collect large liquid spills. Stop leak and contain spill if this can be done safely. Small spillage: Dilute with large quantities of water.

Methods for cleaning up Flush area with flooding quantities of water. Hydrogen peroxide may be decomposed by

adding sodium metabisulfite or sodium sulfite after diluting to about 5%.
HANDLING AND STORAGE

Handling Use only in well-ventilated areas. Keep/Store away from clothing/ combustible materials.

Wear personal protective equipment. Never return unused hydrogen peroxide to original

container. Contamination may cause decomposition and generation of oxygen gas which

could result in high pressures and possible container rupture. Empty drums should be triple

rinsed with water before discarding. Utensils used for handling hydrogen peroxide should

only be made of glass, stainless steel, aluminum or plastic. Pipes and equipment should be

passivated before first use. Hydrogen peroxide should be stored only in vented containers

and transferred only in a prescribed manner.

Storage Keep containers in cool areas out of direct sunlight and away from combustibles. Provide

mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into

work environment. Containers must be vented. Keep/store only in original container. Store

rooms or warehouses should be made of non-combustible materials with impermeable

floors. In case of release, spillage should flow to safe area. Containers should be visually

inspected on a regular basis to detect any abnormalities (swollen drums, increases in

temperature, etc.).

Incompatible products Combustible materials. Copper alloys, galvanized iron. Strong reducing agents. Heavy

metals. Iron. Copper alloys. Contact with metals, metallic ions, alkalis, reducing agents and

organic matter (such as alcohols or terpenes) may produce self-accelerated thermal

decomposition.
EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines Ingredients with workplace control parameters.

Chemical name ACGIH TLV OSHA PEL NIOSH Mexico

Hydrogen peroxide

7722-84-1

TWA: 1 ppm TWA: 1 ppm

TWA: 1.4 mg/m3

IDLH: 75 ppm

TWA: 1 ppm

TWA: 1.4 mg/m3

Mexico: TWA 1 ppm

Mexico: TWA 1.5 mg/m3

Mexico: STEL 2 ppm

Mexico: STEL 3 mg/m3

Chemical name British Columbia Quebec Ontario TWAEV Alberta

Hydrogen peroxide

7722-84-1

TWA: 1 ppm TWA: 1 ppm

TWA: 1.4 mg/m3

TWA: 1 ppm TWA: 1 ppm

TWA: 1.4 mg/m3

Appropriate engineering controls

Engineering measures Ensure that eyewash stations and safety showers are close to the workstation location.

Ensure adequate ventilation.
Individual protection measures, such as personal protective equipment

Eye/Face Protection Use chemical splash-type monogoggles and a full-face shield made of polycarbonate,

acetate, polycarbonate/acetate, PETG or thermoplastic.

Skin and Body Protection For body protection wear impervious clothing such as an approved splash protective suit made of SBR rubber, PVC (PVC Outershell w/Polyester Substrate), Gore-Tex (Polyester

trilaminate w/Gore-Tex), or a specialized HAZMAT Splash or Protective Suite (Level A, B,

or C). For foot protection, wear approved boots made of NBR, PVC, Polyurethane, or

neoprene. Overboots made of Latex or PVC, as well as firefighter boots or specialized

HAZMAT boots are also permitted. DO NOT wear any form of boot or overboot made of

nylon or nylon blends. DO NOT USE cotton, wool or leather as these materials react rapidly

with higher concentrations of hydrogen peroxide. Completely submerge hydrogen peroxide

contaminated clothing or other materials in water prior to drying. Residual hydrogen

peroxide, if allowed to dry on materials such as paper, fabrics, cotton, leather, wood or

other combustibles, can cause the material to ignite and result in a fire.

Hand Protection For hand protection, wear approved gloves made of nitrile, PVC, or neoprene. DO NOT

use cotton, wool or leather for these materials react RAPIDLY with higher concentrations of

hydrogen peroxide. Thoroughly rinse the outside of gloves with water prior to removal.

Inspect regularly for leaks.

Respiratory Protection If concentrations in excess of 10 ppm are expected, use NIOSH/DHHS approved

self-contained breathing apparatus (SCBA) or other approved air-supplied respirator (ASR)

equipment (e.g., a full-face airline respirator (ALR)). DO NOT use any form of air-purifying

respirator (APR) or filtering facepiece (dust mask), especially those containing oxidizable

sorbants such as activated carbon.

Hygiene measures Avoid breathing vapors, mist or gas. Clean water should be available for washing in case of

eye or skin contamination. .

General information Protective engineering solutions should be implemented and in use before personal

protective equipment is considered.
PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Clear, colorless liquid

Physical State Liquid

Color Colorless

Odor odorless

Odor threshold Not applicable

pH <= 3.0 Melting point/freezing point -52 °C Boiling Point/Range 114 °C Flash point Not flammable Evaporation Rate > 1 (n-butyl acetate=1)

Flammability (solid, gas) Not flammable

Flammability Limit in Air Not applicable

Upper flammability limit:

Lower flammability limit:

Vapor pressure 18 mm Hg @ 30 °C

Vapor density No information available

Density 1.2 @ 20 °C

Specific gravity 1.2

Water solubility completely soluble

Solubility in other solvents No information available

Partition coefficient log Kow = -1.5 @ 20 °C

Autoignition temperature Not combustible

Decomposition temperature 100 °C (adiabatic)

Viscosity, kinematic 1.17 cP @ 20 °C

Viscosity, dynamic No information available
Explosive properties No information available

Oxidizing properties Strong oxidizer

Molecular weight 34

Bulk density Not applicable
STABILITY AND REACTIVITY

Reactivity Reactive and oxidizing agent.

Chemical Stability Stable under normal conditions. Decomposes on heating. Stable under recommended

storage conditions.

Possibility of Hazardous Reactions Contact with organic substances may cause fire or explosion. Contact with metals, metallic ions, alkalis, reducing agents and organic matter (such as alcohols or terpenes) may

produce self-accelerated thermal decomposition.

Hazardous polymerization Hazardous polymerization does not occur.

Conditions to avoid Excessive heat; Contamination; Exposure to UV-rays; pH variations.

Incompatible materials Combustible materials. Copper alloys, galvanized iron. Strong reducing agents. Heavy

metals. Iron. Copper alloys. Contact with metals, metallic ions, alkalis, reducing agents and

organic matter (such as alcohols or terpenes) may produce self-accelerated thermal

decomposition.

Hazardous Decomposition Products Oxygen which supports combustion. Liable to produce overpressure in container.
TOXICOLOGICAL INFORMATION

Product Information

LD50 Oral 50% solution: LD50 > 225 mg/kg bw (rat)

35 % solution:LD50 1193 mg/kg bw (rat)

70 % solution: LD50 1026 mg/kg bw (rat)

LD50 Dermal 35% solution: LD50 > 2000 mg/kg bw (rabbit)

70 % solution: LD50 9200 mg/kg bw (rabbit)

LC50 Inhalation 50% solution: LC50 > 170 mg/m3 (rat) (4-hr)

Hydrogen Peroxide vapors: LC0 9400 mg/m³ (mouse) (5 – 15 minutes)

Hydrogen Peroxide vapors: LC50 > 2160 mg/m³ (mouse)

Serious eye damage/eye irritation Corrosive. Risk of serious damage to eyes.

Skin corrosion/irritation Corrosive to skin. Causes severe burns.

Sensitization Did not cause sensitization on laboratory animals.

Information on toxicological effects

Symptoms Vapors, mists, or aerosols of hydrogen peroxide can cause upper airway irritation,

inflammation of the nose, hoarseness, shortness of breath, and a sensation of burning or

tightness in the chest. Prolonged exposure to concentrated vapor or to dilute solutions can

cause irritation and temporary bleaching of skin and hair. Exposure to vapor, mist, or

aerosol can cause stinging pain and tearing of eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Carcinogenicity This product contains hydrogen peroxide. The International Agency for Research on

Cancer (IARC) has concluded that there is inadequate evidence for carcinogenicity of

hydrogen peroxide in humans, but limited evidence in experimental animals (Group 3 – not

classifiable as to its carcinogenicity to humans). The American Conference of

Governmental Industrial Hygienists (ACGIH) has concluded that hydrogen peroxide is a

‘Confirmed Animal Carcinogen with Unknown Relevance to Humans’ (A3).
Chemical name ACGIH IARC NTP OSHA

Hydrogen peroxide

7722-84-1

A3 3

Mutagenicity This product is not recognized as mutagenic by Research Agencies

In vivo tests did not show mutagenic effects

Reproductive toxicity This product is not recognized as reprotox by Research Agencies. No toxicity to

reproduction in animal studies.

STOT – single exposure May cause respiratory irritation.

STOT – repeated exposure Not classified.

Target organ effects Eyes, Respiratory System, Skin.

Aspiration hazard Aspiration risk: may cause lung damage if swallowed.
ECOLOGICAL INFORMATION

Ecotoxicity

Ecotoxicity effects Hydrogen peroxide is naturally produced by sunlight (between 0.1 and 4 ppb in air and

0.001 to 0.1 mg/L in water). Not expected to have significant environmental effects.

Hydrogen peroxide (7722-84-1)

Active Ingredient(s) Duration Species Value Units

Hydrogen peroxide 96 h LC50 Fish Pimephales

promelas

16.4 mg/L

Hydrogen peroxide 72 h LC50 Fish Leuciscus idus 35 mg/L

Hydrogen peroxide 48 h EC50 Daphnia pulex 2.4 mg/L

Hydrogen peroxide 24 h EC50 Daphnia magna 7.7 mg/L

Hydrogen peroxide 72 h EC50 Algae Skeletonema

costatum

1.38 mg/L

Hydrogen peroxide 21 d NOEC Daphnia magna 0.63 mg/L
DISPOSAL CONSIDERATIONS

Waste disposal methods Dispose of in accordance with local regulations. Can be disposed as waste water, when in

compliance with local regulations.

US EPA Waste Number D001 D003

Contaminated Packaging Dispose of in accordance with local regulations.

Drums – Empty as thoroughly as possible. Triple rinse drums before disposal. Avoid

contamination; impurities accelerate decomposition. Never return product to original

container.

Persistence and degradability Hydrogen peroxide in the aquatic environment is subject to various reduction or oxidation processes and decomposes into water and oxygen. Hydrogen peroxide half-life in

freshwater ranged from 8 hours to 20 days, in air from 10 – 20 hours, and in soils from

minutes to hours depending upon microbiological activity and metal contamination.

Bioaccumulation Material may have some potential to bioaccumulate but will likely degrade in most

environments before accumulation can occur.

Mobility Will likely be mobile in the environment due to its water solubility but will likely degrade over

time.
Other Adverse Effects Decomposes into oxygen and water. No adverse effects.

Hydrogen Peroxide 50%

TRANSPORT INFORMATION

DOT

UN/ID no UN 2014

Proper Shipping Name HYDROGEN PEROXIDE, AQUEOUS SOLUTION

Hazard class 5.1

Subsidiary class 8

Packing Group II

TDG

UN/ID no UN 2014

Proper Shipping Name HYDROGEN PEROXIDE, AQUEOUS SOLUTION

Hazard class 5.1

Subsidiary class 8

Packing Group II

ICAO/IATA Hydrogen peroxide (>40%) is forbidden on Passenger and Cargo Aircraft. Air regulation

permit shipment of Hydrogen Peroxide (<=40%) in non-vented containers for Air Cargo Only aircraft, as well as for Passenger and Cargo aircraft. HOWEVER, all Hydrogen Peroxide containers are vented and therefore, air shipments of H2O2 are not permitted. IATA air regulations state that venting of packages containing oxidizing substances is not permitted for air transport. IMDG/IMO UN/ID no UN 2014 Proper Shipping Name HYDROGEN PEROXIDE, AQUEOUS SOLUTION Hazard class 5.1 Subsidiary Hazard Class 8 Packing Group II OTHER INFORMATION Protect from physical damage. Keep drums in upright position. Drums should not be stacked in transit. Do not store drums on wooden pallets. 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic health hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA Chemical name Hazardous Substances RQs Extremely Hazardous Substances RQs SARA RQ Hydrogen peroxide 7722-84-1 1000 lb Hydrogen Peroxide RQ is for concentrations of > 52% only

International Inventories

Component TSCA

(United States)

DSL

(Canada)

EINECS/EL

INCS

(Europe)

ENCS

(Japan)

China

(IECSC)

KECL

(Korea)

PICCS

(Philippines)

AICS

(Australia)

NZIoC

(New Zealand)

Hydrogen peroxide

7722-84-1 ( 50 )

X X X X X X X X X

Mexico – Grade Serious risk, Grade 3

CANADA

WHMIS Hazard Class C – Oxidizing materials

D1B – Toxic materials

E – Corrosive material

F – Dangerously reactive material
OTHER INFORMATION

NFPA/HMIS Ratings Legend

Uniform Fire Code

Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0

Special Hazards: OX = Oxidizer

Protection = H (Safety goggles, gloves, apron, the use of supplied air or SCBA respirator is

required in lieu of a vapor cartidge respirator)

Oxidizer: Class 2–Liquid

NFPA Health Hazards 3 Flammability 0 Stability 1 Special Hazards OX

HMIS Health Hazards 3 Flammability 0
Physical hazard 1 Personal Protection H